Efficient Catalysts Based on Substitutional Solid Solutions and Palladium Intermetallic Compounds for the Selective Hydrogenation of Acetylene to Ethylene

Efficient Catalysts Based on Substitutional Solid Solutions and Palladium Intermetallic Compounds for the Selective Hydrogenation of Acetylene to Ethylene Научная публикация

Журнал

Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555

Вых. Данные

Год: 2024, Том: 16, Номер: 3, Страницы: 278-311 Страниц : 34 DOI: 10.1134/S2070050424700156

Ключевые слова

palladium, catalyst, acetylene hydrogenation to ethylene, substitutional solid solutions, nanoalloys, intermetallic compounds, geometric effect, electronic effect, Pd–Ag, Pd–Cu, Pd–Au, Pd–Ga, Pd–Zn

Авторы

Shlyapin D.A. ¹ , Yurpalova D.V. ¹ , Afonasenko T.N. ¹ , Temerev V.L. ¹ , Lavrenov A.V. ¹

Организации

1	Center of New Chemical Technologies, Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences

Информация о финансировании (1)

Министерство науки и высшего образования Российской Федерации

FWUR-2024-0039

Features of the catalytic action of Pd–Ag, Pd–Cu, Pd–Au, Pd–Ga, and Pd–Zn bimetallic systems on the acetylene conversion to ethylene are discussed taking into account two factors that determine the effect of the second metal on palladium, namely, the “ensemble effect” (geometric effect) and the “ligand effect” (electronic effect). The relationship between the calculated thermodynamic and kinetic parameters of the adsorption interaction of major reaction medium components and intermediates with the catalyst surface, the structure of active ensembles, and characteristics determined in tests, such as the structural parameters of bimetallic phases, the electronic state of their components, and catalytic properties, is shown. Some examples are given to show that the modifier atoms can be incorporated into active ensembles and the sites formed by the modifier atoms can be involved in the catalysis of individual elementary steps.

Shlyapin D.A. , Yurpalova D.V. , Afonasenko T.N. , Temerev V.L. , Lavrenov A.V.
Efficient Catalysts Based on Substitutional Solid Solutions and Palladium Intermetallic Compounds for the Selective Hydrogenation of Acetylene to Ethylene
Catalysis in Industry. 2024. V.16. N3. P.278-311. DOI: 10.1134/S2070050424700156 WOS OpenAlex

Шляпин Д.А. , Юрпалова Д.В. , Афонасенко Т.Н. , Темерев В.Л. , Лавренов А.В.
Эффективные катализаторы селективного гидрирования ацетилена в этилен на основе твердых растворов замещения и интерметаллических соединений палладия
Катализ в промышленности. 2023. Т.23. №6. С.17-51. DOI: 10.18412/1816-0387-2023-6-17-51 РИНЦ OpenAlex

Поступила в редакцию:	30 июн. 2023 г.
Принята к публикации:	4 сент. 2023 г.

Web of science:	WOS:001315700900006
OpenAlex:	W4402716797

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