Effect of preparation conditions of nanocrystalline Pd/MgO catalysts on their performance in selective hydrogenation of acetylene Full article
| Journal |
Molecular Catalysis
ISSN: 2468-8231 |
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| Output data | Year: 2024, Volume: 560, Article number : 114151, Pages count : 12 DOI: 10.1016/j.mcat.2024.114151 | ||||||
| Tags | Sol-gel synthesisMagnesium oxideAerogelsXerogelsPalladium nanoparticlesAcetylene hydrogenation | ||||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Ministry of Science and Higher Education of the Russian Federation | FWUR-2024-0039 |
| 2 | Ministry of Science and Higher Education of the Russian Federation | FWUR-2024-0034 |
Abstract:
In the present work, an alkoxide sol-gel method was applied to prepare Pd/MgO catalysts. The sol-gel procedure was followed by supercritical drying (aerogels) or conventional drying (xerogels) in a furnace. These materials were compared with the impregnated samples. The Pd loading was 1 wt% in all the cases. The as-prepared catalysts were characterized by a set of physicochemical methods. Both the type of the Pd precursor and the preparation route were found to affect the porous structure of the materials as well as the dispersion of the palladium particles and their localization over the MgO support. Both the xerogel and incipient wetness impregnation methods lead to a narrower pore size distribution in comparison to the aerogel technique. The most dispersed particles with an average size of ∼ 2.0–2.2 nm were observed for the samples prepared by xerogel and impregnation methods. In the case of aerogel-prepared samples, metallic palladium particles possess bimodal distribution with average diameters of 4.3 and 8.4 nm. The best catalytic performance in acetylene hydrogenation to ethylene (50 % acetylene conversion at 37 °C with selectivity ∼60 %) was observed for the Pd/MgO catalyst prepared via the aerogel route using [Pd(NH3)4](NO3)2. Compared to other samples, this material is characterized by relatively weak metal-support interactions and the availability of active sites for reactants, which ensures the kinetic mode of the hydrogenation reaction (Ea = 74.9 kJ/mol).
Cite:
Ilyina E.V.
, Yurpalova D.V.
, Shlyapin D.A.
, Veselov G.B.
, Shivtsov D.M.
, Stoyanovskii V.O.
, Bukhtiyarov A.V.
, Vedyagin A.A.
Effect of preparation conditions of nanocrystalline Pd/MgO catalysts on their performance in selective hydrogenation of acetylene
Molecular Catalysis. 2024. V.560. 114151 :1-12. DOI: 10.1016/j.mcat.2024.114151 WOS Scopus РИНЦ OpenAlex
Effect of preparation conditions of nanocrystalline Pd/MgO catalysts on their performance in selective hydrogenation of acetylene
Molecular Catalysis. 2024. V.560. 114151 :1-12. DOI: 10.1016/j.mcat.2024.114151 WOS Scopus РИНЦ OpenAlex
Dates:
| Submitted: | Feb 28, 2024 |
| Accepted: | Apr 12, 2024 |
| Published online: | Apr 15, 2024 |
| Published print: | May 1, 2024 |
Identifiers:
| Web of science: | WOS:001230041900001 |
| Scopus: | 2-s2.0-85190255362 |
| Elibrary: | 67278701 |
| OpenAlex: | W4394834726 |