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Effect of activation temperature on porous structure of carbon derived from petroleum asphalt Научная публикация

Конференция 12-ая международная научно-техническая конференция "Техника и технология нефтехимического и нефтегазового производства"
16-19 февр. 2022 , Омск
Журнал AIP Conference Proceedings
ISSN: 0094-243X , E-ISSN: 1551-7616
Вых. Данные Год: 2023, Том: 2784, Номер: 1, Номер статьи : 020008-1, Страниц : 7 DOI: 10.1063/5.0140541
Авторы Gorbunova O.V. 1 , Baklanova O.N. 1 , Gulyaeva T.I. 1 , Trenikhin M.V. 1
Организации
1 Center of New Chemical Technologies BIC, Boreskov Institute of Catalysis

Информация о финансировании (1)

1 Министерство науки и высшего образования Российской Федерации 0239-2021-0012

Реферат: e report on petroleum asphalt–based porous carbons with high textural characteristics, CO2/N2 adsorption capacity and selectivity. A series of samples was prepared by a two-stage method, including preliminary heat treatment of asphalt at 450°C and KOH activation. The activation temperature varied from 700 to 900°C. Correlation between the porous structure and adsorption properties of asphalt-based porous carbons on the activation temperature was obtained. The activation temperature of petroleum asphalt has a significant effect on the porous structure of the activated carbon materials. Thus, exclusively microporous sample is formed at the temperature of 700 °С. An increase in the activation temperature to 800°C leads to the formation of mesopores. The decrease in textural characteristics due to the formation of more stable carbon structures to gasification reactions takes place at a temperature of 900 °С. In addition, the adsorption capacity of CO2 was measured for carbon samples. The porous carbon activated at 700 °C and derived from petroleum asphalt exhibited high CО2 adsorption capacity of 6.3 mmol/g at 0 °C and 1 atm and good selectivity for CO2 over N2, indicating possible applications in CO2 capture technology.
Библиографическая ссылка: Gorbunova O.V. , Baklanova O.N. , Gulyaeva T.I. , Trenikhin M.V.
Effect of activation temperature on porous structure of carbon derived from petroleum asphalt
AIP Conference Proceedings. 2023. V.2784. N1. 020008-1 :1-7. DOI: 10.1063/5.0140541 Scopus OpenAlex
Даты:
Поступила в редакцию: 28 дек. 2022 г.
Принята к публикации: 17 февр. 2023 г.
Опубликована в печати: 26 июл. 2023 г.
Опубликована online: 26 июл. 2023 г.
Идентификаторы БД:
Scopus: 2-s2.0-85176778610
OpenAlex: W4385270740
Цитирование в БД:
БД Цитирований
OpenAlex 1
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