Influence of Environmental Conditions on Carbon Black Oxidation by Reactive Oxygen Intermediates Научная публикация
Конференция |
5-ая международная научно-техническая конференция "Техника и технология нефтехимического и нефтегазового производства" 25-30 апр. 2015 , Омск |
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Журнал |
Procedia Engineering
ISSN: 1877-7058 |
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Вых. Данные | Год: 2015, Номер: 113, Страницы: 43-50 Страниц : 8 DOI: 10.1016/j.proeng.2015.07.287 | ||||
Ключевые слова | carbon black; oxidation; hydrogen peroxide; ozone; singlet oxygen; functional groups | ||||
Авторы |
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Организации |
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Реферат:
The paper examined the influence of hydrogen peroxide and ozone and singlet oxygen co-agents on the functional groups of the carbon black surface. The influence of the ambient temperature and the concentration of the reactants on protogenic functional groups (carboxylic and phenolic) generating has been studied. To assess the functional composition methods of titration with alkali of different strengh, differential potentiometer, pyrolysis gas chromatography have been used. It was found that the carbon oxidation depends on the sample structure. It is shown that carbon oxidation with hydrogen peroxide depends on the co-agent nature. With singlet oxygen used as a co-agent, carboxyl groups with the lowest pKa of about 2are generated on the carbon surface. When using ozone pKa of the group is higher than 2
Библиографическая ссылка:
Razdyakonova G.I.
, Kokhanovskaya O.A.
, Likholobov V.A.
Influence of Environmental Conditions on Carbon Black Oxidation by Reactive Oxygen Intermediates
Procedia Engineering. 2015. N113. P.43-50. DOI: 10.1016/j.proeng.2015.07.287 WOS Scopus РИНЦ OpenAlex
Influence of Environmental Conditions on Carbon Black Oxidation by Reactive Oxygen Intermediates
Procedia Engineering. 2015. N113. P.43-50. DOI: 10.1016/j.proeng.2015.07.287 WOS Scopus РИНЦ OpenAlex
Файлы:
Полный текст от издателя
Идентификаторы БД:
Web of science: | WOS:000380445300008 |
Scopus: | 2-s2.0-84984891641 |
РИНЦ: | 27570416 |
OpenAlex: | W1108935097 |