In Situ Formation of Al(Fe)/Cl Metal Chloride Complexes and Evaluation of Their Catalytic Properties in the Reaction of Ethylene Oligomerization

In Situ Formation of Al(Fe)/Cl Metal Chloride Complexes and Evaluation of Their Catalytic Properties in the Reaction of Ethylene Oligomerization Full article

Journal

Russian Journal of Applied Chemistry
ISSN: 1070-4272 , E-ISSN: 1608-3296

Output data

Year: 2017, Volume: 90, Number: 12, Pages: 1926-1930 Pages count : 5 DOI: 10.1134/s1070427217120059

Authors

Arbuzov A.B. ^1,2 , Kudrya E.N. ¹ , Trenikhin M.V. ^1,2 , Drozdov V.A. ¹

Affiliations

1	Institute of Hydrocarbons Processing, Siberian Branch, Russian Academy of Sciences
2	Omsk Scientific Center, Siberian Branch, Russian Academy of Sciences

Funding (1)

Ministry of Science and Higher Education of the Russian Federation

46.2.5

According to FT-IR and UV spectroscopic data, the interaction of the Al/Fe alloy with tert-butyl chloride results in that AlCl4–, Al2Cl7–, and FeCl2+ ion complexes, Fe3+ ions, and AlCl3 molecular form are produced insitu in the reaction medium. Ethylene was oligomerized in n-hexane on metal chloride complexes produced in situ from Al/Fe alloys and tert-butyl chloride.

Arbuzov A.B. , Kudrya E.N. , Trenikhin M.V. , Drozdov V.A.
In Situ Formation of Al(Fe)/Cl Metal Chloride Complexes and Evaluation of Their Catalytic Properties in the Reaction of Ethylene Oligomerization
Russian Journal of Applied Chemistry. 2017. V.90. N12. P.1926-1930. DOI: 10.1134/s1070427217120059 WOS Scopus РИНЦ OpenAlex

Арбузов А.Б. , Кудря Е.Н. , Тренихин М.В. , Дроздов В.А.
Формирование in situ металл-хлоридных комплексов Al(Fe)/Cl и оценка их каталитических свойств в реакции олигомеризации этилена
Журнал прикладной химии. 2017. Т.90. №12. С.1595-1599. РИНЦ

Submitted:	Nov 7, 2017
Published print:	Dec 1, 2017
Published online:	Apr 25, 2018

Web of science:	WOS:000429566300005
Scopus:	2-s2.0-85045282105
Elibrary:	35508956
OpenAlex:	W2801017423

DB	Citing
Scopus	4
Web of science	3
Elibrary	1
OpenAlex	4