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Isomerization of alkanes over bifunctional Pt(Pd)/WO3-ZrO2 catalysts Full article

Conference 11-я международная научно-техническая конференция "Техника и технология нефтехимического и нефтегазового производства"
24-27 Feb 2021 , Омск
Journal AIP Conference Proceedings
ISSN: 0094-243X , E-ISSN: 1551-7616
Output data Year: 2021, Volume: 2412, Article number : 020011, Pages count : 6 DOI: 10.1063/5.0075226
Authors Shkurenok V.A. 1 , Smolikov M.D. 1 , Kir'yanov D.I. 1 , Belyi A.S. 1
Affiliations
1 Center of New Chemical Technologies BIC, Boreskov Institute of Catalysis

Funding (1)

1 Ministry of Science and Higher Education of the Russian Federation 0239-2021-0006

Abstract: The effect of the Pd and Pt addition into WO3-ZrO2 catalyst on the isomerization reaction of C6-C7 alkanes mixture in the range of LHSV = 0.5-4 h-1 is studied. The best reaction performance is achieved on Pd/WO3-ZrO2 catalyst at a temperature of 170°C and LHSV = 1 h-1: the yield of heptane isomers is 67.2 wt.% (including DTMS – 26.5 wt.%) at heptane conversion of 86.4%; the yield of hexane isomers is 53.7 wt.% (including DMB – 8.9 wt.%) at hexane conversion of 57.3%. In this case, the RON of the obtained isomerate is 55 points and the yield of stable catalyzate C5+ is 89.8 wt.%.
Cite: Shkurenok V.A. , Smolikov M.D. , Kir'yanov D.I. , Belyi A.S.
Isomerization of alkanes over bifunctional Pt(Pd)/WO3-ZrO2 catalysts
AIP Conference Proceedings. 2021. V.2412. 020011 :1-6. DOI: 10.1063/5.0075226 Scopus РИНЦ OpenAlex
Dates:
Published online: Dec 10, 2021
Identifiers:
Scopus: 2-s2.0-85122280609
Elibrary: 47893049
OpenAlex: W4206700256
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