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A study of the liquid pyrolysis products of a propane-butane mixture as a precursor in the synthesis of cellular carbon foam Научная публикация

Журнал Journal of Analytical and Applied Pyrolysis
ISSN: 0165-2370
Вых. Данные Год: 2021, Том: 159, Номер статьи : 105328, Страниц : 9 DOI: 10.1016/j.jaap.2021.105328
Ключевые слова pyrolysis, propane-butane mixture, pyrolytic liquid products, polyaromatic compounds, cellular carbon foam
Авторы Raiskaya Еvgenia А. 1 , Krivonos Oksana I. 1 , Babenko Аnna V. 1 , Belskaya Olga B. 1
Организации
1 Center of New Chemical Technologies BIC, Boreskov Institute of Catalysis

Информация о финансировании (1)

1 Министерство науки и высшего образования Российской Федерации 0239-2021-0004

Реферат: The chemical composition of the pyrolytic liquid products (PLP) of the propane-butane mixture, which serve as a precursor in the synthesis of carbon foam with the cellular structure (a cellular carbon material), was studied. PLP were shown to be a mixture of hydrocarbons containing 95 wt.% carbon and 4 wt.% hydrogen, which testify to the presence of polycyclic aromatic compounds. A study by means of sequential extraction, structural-group analysis and chromato-mass spectrometry revealed the heterogeneous nature of PLP components and detected both the lighter fractions (14 wt.%) soluble in alkanes and the polynuclear aromatic compounds (72 wt.%) soluble in chloroform. The averaged PLP molecule with the molecular weight 240 аmu contains approximately twenty carbon atoms that form polynuclear structures including five aromatic rings. The following main components were identified: naphthalene, 1,1′-biphenyl, acenaphthylene, 9H-fluorene, anthracene, phenanthrene, fluoranthene, pyrene, acepyrene, triphenylene, benz[e]acefenantrylene, benzopyrene, and benzo[ghi]perylene.
Библиографическая ссылка: Raiskaya Е.А. , Krivonos O.I. , Babenko А.V. , Belskaya O.B.
A study of the liquid pyrolysis products of a propane-butane mixture as a precursor in the synthesis of cellular carbon foam
Journal of Analytical and Applied Pyrolysis. 2021. V.159. 105328 :1-9. DOI: 10.1016/j.jaap.2021.105328 WOS Scopus РИНЦ OpenAlex
Даты:
Поступила в редакцию: 8 июн. 2021 г.
Принята к публикации: 10 сент. 2021 г.
Опубликована online: 17 сент. 2021 г.
Опубликована в печати: 1 окт. 2021 г.
Идентификаторы БД:
Web of science: WOS:000711631100001
Scopus: 2-s2.0-85115343208
РИНЦ: 46578615
OpenAlex: W3199752831
Цитирование в БД:
БД Цитирований
Scopus 3
OpenAlex 5
Альметрики: