The microstructure and properties of framework zirconium phosphates based nanocomposites – catalysts of alkane isomerization

The microstructure and properties of framework zirconium phosphates based nanocomposites – catalysts of alkane isomerization Full article

Journal

Materials Research Innovations
ISSN: 1432-8917 , E-ISSN: 1433-075X

Output data

Year: 2000, Volume: 3, Number: 5, Pages: 276-285 Pages count : 10 DOI: 10.1007/s100190000051

Tags

Nanocomposites · Framework zirconium phosphates · Supported nanoparticles of WO3 · MoO3 and Pt · Catalysis of pentane and hexane isomerization

Authors

Sadykov Vladislav A. ¹ , Pavlova Svetlana N. ¹ , Zabolotnaya Galina V. ¹ , Maximovskaya Raisa I. ¹ , Kochubei Dmitrii I. ¹ , Kriventsov Vladimir V. ¹ , Odegova Galina V. ¹ , Ostrovskii N.M. ² , Bel’skaya Olga B. ² , Duplyakin Valerii K. ² , Zaikovskii Vladimir I. ¹ , Paukshtis Eugenii A. ¹ , Burgina Elena B. ¹ , Tsybulya Sergei V. ¹ , Chaikina M.V. ³ , Kuznetsova N.N. ⁴ , Lunin V.V. ⁴ , Roy R. ⁵ , Agrawal D.K. ⁵

Affiliations

1	Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences
2	Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences
3	Institute of Solid State Chemistry, Siberian Branch of the Russian Academy of Sciences
4	Chemical Department, Lomonosov Moscow State University
5	The Pennsylvania State University

Nanocomposites based upon framework zirconium phosphates with supported WO3, MoO3 and Pt nanoparticles were synthesized via the incipient wetness impregnation of high-surface-area mesoporous phosphate samples with water solutions of corresponding salts followed by drying and calcination. The structure and surface properties of nanocomposites were studied by using combination of structural and spectral methods. Due to a strong interaction between supports and supported species, the structure of the latter differs considerably from that of the bulk phases. Surface acid centers typical for zirconium phosphates disappear suggesting their participation in bonding nanoparticles of promoters. Instead, new types of strong acid sites associated with tungsten oxide clusters emerge. The effect of these promoters on performance of zirconium phosphates in the reaction of pentane and hexane isomerization is considered.

Sadykov V.A. , Pavlova S.N. , Zabolotnaya G.V. , Maximovskaya R.I. , Kochubei D.I. , Kriventsov V.V. , Odegova G.V. , Ostrovskii N.M. , Bel’skaya O.B. , Duplyakin V.K. , Zaikovskii V.I. , Paukshtis E.A. , Burgina E.B. , Tsybulya S.V. , Chaikina M.V. , Kuznetsova N.N. , Lunin V.V. , Roy R. , Agrawal D.K.
The microstructure and properties of framework zirconium phosphates based nanocomposites – catalysts of alkane isomerization
Materials Research Innovations. 2000. V.3. N5. P.276-285. DOI: 10.1007/s100190000051 WOS Scopus РИНЦ OpenAlex

Submitted:	Feb 20, 2000
Accepted:	Mar 15, 2000
Published print:	Jun 1, 2000
Published online:	Oct 13, 2016

Web of science:	WOS:000165394300009
Scopus:	2-s2.0-0034195375
Elibrary:	13343772
OpenAlex:	W3159964597

DB	Citing
Scopus	4
OpenAlex	5