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Isomerization of n-heptane on platinum-zeolite catalysts promoted by chlorine and fluorine Full article

Journal Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171
Output data Year: 2020, Volume: 69, Number: 9, Pages: 1709-1713 Pages count : 5 DOI: 10.1007/s11172-020-2952-y
Tags isomerization, n-heptane, zeolite, alumina, zeolite BEA, chlorine, fl uorine.
Authors I. M. Kalashnikov 1 , E. A. Belopukhov 1 , M. D. Smolikov 1 , D. I. Kir´yanov 1 , T. I. Gulyaeva 1 , A. S. Belyi 1
Affiliations
1 Center of New Chemical Technologies BIC, Boreskov Institute of Catalysis

Abstract: The isomerization of n-heptane on BEA supported platinum catalysts with the addition of chlorine and fl uorine as promoters was studied. The use of the halides decreased the operating temperature of the n-heptane conversion. The samples prepared at the stage of peptization showed an increase in the total conversion accompanied by a decrease in the yield of heptane isomers of 6 for chlorine and 27 wt.% for fl uorine. Promotion by the halides at the stage of platinum application led to an increase in the catalyst activity without decrease in the selectivity values.
Cite: I. M. Kalashnikov , E. A. Belopukhov , M. D. Smolikov , D. I. Kir´yanov , T. I. Gulyaeva , A. S. Belyi
Isomerization of n-heptane on platinum-zeolite catalysts promoted by chlorine and fluorine
Russian Chemical Bulletin. 2020. V.69. N9. P.1709-1713. DOI: 10.1007/s11172-020-2952-y WOS Scopus РИНЦ OpenAlex
Original: И. М. Калашников , Е. А. Белопухов , М. Д. Смоликов , Д. И. Кирьянов , Т. И. Гуляева , А. С. Белый
Изомеризация н-гептана на платино-цеолитных катализаторах, промотированных хлором и фтором
Известия Академии наук. Серия химическая. 2020. №9. С.1709-1713. РИНЦ
Dates:
Submitted: Oct 1, 2019
Accepted: Apr 21, 2020
Published print: Sep 1, 2020
Published online: Oct 10, 2020
Identifiers:
Web of science: WOS:000576572500009
Scopus: 2-s2.0-85092377408
Elibrary: 45238107
OpenAlex: W3092602023
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