One-Stage Synthesis of Propylene from Ethylene Using PdRe2O7/B2O3Al2O3 Catalyst

One-Stage Synthesis of Propylene from Ethylene Using PdRe2O7/B2O3Al2O3 Catalyst Full article

Journal

Chemistry for Sustainable Development
, E-ISSN: 1817-1818

Output data

Year: 2013, Volume: 21, Pages: 47-51 Pages count : 5

Tags

palladium sorption, ethylene, propylene, oligomerization, metathesis

Authors

Buluchevskii E.A. ¹ , Mikhailova M.S. ¹ , Lavrenov A.V. ¹

Affiliations

1	Institute of Hydrocarbons Processing, Siberian Branch of the Russian Academy of Sciences, Ul. Neftezàvodskàya 54, Omsk 644040 (Russia)

Equilibrium was investigated concerning the sorption of palladium from the H2PdCl4 and Pd(NH3)4Cl2 solutions onto B2O3Al2O3 carrier. It is demonstrated that the sorption equilibrium is described by Langmuir equation. According the results of testing the Pd/B2O3Al2O3 samples in the course of oligomerization it has been found that the optimum content of palladium in the catalyst should be equal to 0.5 mass %, whereas the optimum precursor of palladium should be presented by palladium chloride complex. The catalytic properties of PdRe2O7/B2O3Al2O3 system in the one-stage propylene synthesis from ethylene were studied. It has been demonstrated that it is possible to obtain propylene with the yield equal to 77 83 % with respect to the theoretically determined one

Buluchevskii E.A. , Mikhailova M.S. , Lavrenov A.V.
One-Stage Synthesis of Propylene from Ethylene Using PdRe2O7/B2O3Al2O3 Catalyst
Chemistry for Sustainable Development. 2013. V.21. P.47-51. РИНЦ

Булучевский Е.А. , Михайлова М.С. , Лавренов А.В.
Одностадийный синтез пропилена из этилена на катализаторе Pd-Re2O7/B2O3-Al2O3
Химия в интересах устойчивого развития. 2013. Т.21. №1. С.55-59. РИНЦ

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