Sciact
  • EN
  • RU

Joint transformations of H-dodecane and 2-methylthiophene on bizeolite cracking catalysts containing phosphorus-modified zeolite ZSM-5 Full article

Conference VI Всероссийская научная молодежная школа-конференция «Химия под знаком СИГМА: исследования, инновации, технологии"
18-20 May 2020 , Омск
Journal AIP Conference Proceedings
ISSN: 0094-243X , E-ISSN: 1551-7616
Output data Year: 2020, Volume: 2301, Pages: 040008 Pages count : 8 DOI: 10.1063/5.0032913
Authors Plekhova K.S. 1 , Yurtaeva A.S. 1 , Gulyaeva T.I. 1 , Potapenko O.V. 1 , Sorokina T.P. 1 , Doronin V.P. 1
Affiliations
1 Center of New Chemical Technologies BIC, Boreskov Institute of Catalysis

Funding (1)

1 Ministry of Science and Higher Education of the Russian Federation 46.2.4

Abstract: The effect of the phosphorus in zeolite ZSM-5 as a component of cracking catalysts, was studied on the conversion of pure n-dodecane, as well as its mixture with 2-methylthiophene in an amount of 5000 ppm sulfur. It was established that the modification of zeolite ZSM-5 with phosphorus affects the catalytic activity of catalysts based on it. The maximum yield of C2-C4-olefinic hydrocarbons is observed at a phosphorus content of 4 wt. % in zeolite ZSM-5. Modification of zeolite ZSM-5 with phosphorus reduces the degree of conversion of thiophene compounds by reducing the contribution of intermolecular hydrogen transfer and as a result increasing the content of sulfur compounds in cracking liquid products.
Cite: Plekhova K.S. , Yurtaeva A.S. , Gulyaeva T.I. , Potapenko O.V. , Sorokina T.P. , Doronin V.P.
Joint transformations of H-dodecane and 2-methylthiophene on bizeolite cracking catalysts containing phosphorus-modified zeolite ZSM-5
AIP Conference Proceedings. 2020. V.2301. P.040008. DOI: 10.1063/5.0032913 Scopus РИНЦ OpenAlex
Identifiers:
Scopus: 2-s2.0-85098073342
Elibrary: 45062871
OpenAlex: W3113175218
Citing:
DB Citing
Scopus 1
OpenAlex 1
Altmetrics: