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Hydrodeoxygenation of vegetable oil on M/WO3-Al2O3 (M = NiMo, Pt, Pd, Ni) catalysts for producing biofuels Full article

Conference VI Всероссийская научная молодежная школа-конференция «Химия под знаком СИГМА: исследования, инновации, технологии"
18-20 May 2020 , Омск
Journal AIP Conference Proceedings
ISSN: 0094-243X , E-ISSN: 1551-7616
Output data Year: 2020, Volume: 2301, Article number : 020002, Pages count : 8 DOI: 10.1063/5.0032890
Authors Nepomniashchii A.A. 1 , Buluchevskiy E.A. 1 , Yurpalov V.L. 1 , Drozdov V.A. 1 , Lavrenov A.V. 1
Affiliations
1 Center of New Chemical Technologies BIC, Boreskov Institute of Catalysis

Funding (1)

1 Ministry of Science and Higher Education of the Russian Federation V. 47

Abstract: Hydrodeoxygenation of sunflower oil on M/WO3-Al2O3 (M = NiMo, Pt, Pd, Ni) catalysts prepared by incipient wetness impregnation was investigated. The metal deposited on WO3-Al2O3 affects the main directions of the conversion of raw materials, and, consequently, the yield and composition of the products. The low dispersion of monometallic catalysts and high Brønsted acidity promote oxygen removal along the direct hydrodeoxygenation (HDO) route. Unlike monometallic systems, triglyceride hydrocracking on NiMoS/WO3-Al2O3 catalysts proceeds with the formation of propane as the main by-product. The high activity of the NiMoS/WO3-Al2O3 catalyst in hydrogenation and ecarbonylation/decarboxylation (deCOx) reactions results in lower yields of liquid hydrocarbon product.
Cite: Nepomniashchii A.A. , Buluchevskiy E.A. , Yurpalov V.L. , Drozdov V.A. , Lavrenov A.V.
Hydrodeoxygenation of vegetable oil on M/WO3-Al2O3 (M = NiMo, Pt, Pd, Ni) catalysts for producing biofuels
AIP Conference Proceedings. 2020. V.2301. 020002 :1-8. DOI: 10.1063/5.0032890 Scopus РИНЦ OpenAlex
Dates:
Published online: Dec 8, 2020
Identifiers:
Scopus: 2-s2.0-85098083761
Elibrary: 45062700
OpenAlex: W3111922611
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