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Effect of mixed oxide cracking catalyst on conversion of the mixture of vacuum gas oil and vegetable oil Full article

Journal Petroleum Chemistry
ISSN: 0965-5441 , E-ISSN: 1531-8532
Output data Year: 2021, Volume: 61, Number: 1, Pages: 60-66 Pages count : 7 DOI: 10.1134/S0965544121010060
Tags cracking catalysts, mixed oxides, vacuum gas oil, vegetable oil
Authors Lipin P.V. 1 , Potapenko O.V. 1 , Sorokina T.P. 1 , Doronin V.P. 1
Affiliations
1 Center of New Chemical Technologies BIC, Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences

Funding (1)

1 Ministry of Science and Higher Education of the Russian Federation 0239-2021-0006

Abstract: A number of cracking catalyst samples containing Me–Mg–Al mixed oxides have been prepared. Cobalt, zinc, copper, and cerium were used as additional metals in the mixed oxide composition. When studying the cracking of a vacuum gas oil–sunfl ower oil mixture, catalysts containing Co–Mg–Al or Zn–Mg–Al mixed oxides were found to increase both the conversion rate of the mixed feedstock by 5.0 wt % compared to a sample containing the mixed oxide free of additional metal, and the gasoline yield by 1.6–3.0 wt %. It was discovered that the modifi cation of mixed oxides with cobalt or zinc cations has no signifi cant effect on the distribution of inorganic products, thereby indicating sustained catalytic activity during the decarboxylation reaction. The catalytic tests also demonstrated that catalyst samples containing mixed Mg–Al oxides with copper cations exhibited enhanced decarbonylation effect, as well as low conversion rates of the mixed feedstock and low gasoline yield, which is probably associated with the poisoning impact of copper oxide on Y zeolite.
Cite: Lipin P.V. , Potapenko O.V. , Sorokina T.P. , Doronin V.P.
Effect of mixed oxide cracking catalyst on conversion of the mixture of vacuum gas oil and vegetable oil
Petroleum Chemistry. 2021. V.61. N1. P.60-66. DOI: 10.1134/S0965544121010060 WOS Scopus РИНЦ OpenAlex
Original: Липин П.В. , Потапенко О.В. , Сорокина Т.П. , Доронин В.П.
Влияние смешанного оксида в составе катализатора крекинга на совместное превращение вакуумного газойля с растительным маслом
Нефтехимия. 2021. Т.61. №1. С.70-77. DOI: 10.31857/S0028242121010068 РИНЦ OpenAlex
Dates:
Submitted: May 29, 2020
Accepted: Sep 18, 2020
Published print: Jan 1, 2021
Identifiers:
Web of science: WOS:000591942800001
Scopus: 2-s2.0-85096430574
Elibrary: 45171390
OpenAlex: W3109236017
Citing:
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Scopus 1
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