Polyvinyl Chloride as a Precursor for Low-Temperature Synthesis of Carbon Materials

Polyvinyl Chloride as a Precursor for Low-Temperature Synthesis of Carbon Materials Full article

Journal

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Output data

Year: 2016, Volume: 65, Number: 11, Pages: 2712-2717 Pages count : 6 DOI: 10.1007/s11172-016-1640-4

Tags

polyvinyl chloride, carbon materials, conjugated polymers, polyvinylenes, waste recycling.

Authors

Solodovnichenko V. S. ^1,2 , Kryazhev Yu. G. ^1,2 , Arbuzov A. B. ² , Talzi V. P. ² , Antonicheva N. V. ^1,2 , Drozdov V. A. ^1,2 , Zapevalova E. S. ² , Likholobov V. A. ^1,2

Affiliations

1	Omsk Scientific Center of Siberian Branch of Russian Academy of Sciences, 15 prosp. Marksa, 644024 Omsk, Russian Federation
2	Institute of Hydrocarbons Processing of Siberian Branch of Russian Academy of Sciences, 54 ul. Neftezavodskaya, 644040 Omsk, Russian Federation

Funding (1)

Russian Science Foundation

14-33-00018

A method for carbon materials synthesis based on polyvinyl chloride has been proposed. Method includes polymer dehydrochlorination by alkali with carbonrich conjugated structures (polyvinylenes) formation and its subsequent carbonization at relatively low temperatures. Raman and 13C NMR spectroscopy and transmission electron microscopy show that thermal treatment of the resulting polyvinylenes up to 400 °C leads to the formation of amorphous carbon material with chlorine contain less than 0.5 wt.%. These results can be used to develop dioxinfree technology of utilization of polyvinyl chloride and its wastes.

Solodovnichenko V.S. , Kryazhev Y.G. , Arbuzov A.B. , Talzi V.P. , Antonicheva N.V. , Drozdov V.A. , Zapevalova E.S. , Likholobov V.A.
Polyvinyl Chloride as a Precursor for Low-Temperature Synthesis of Carbon Materials
Russian Chemical Bulletin. 2016. V.65. N11. P.2712-2717. DOI: 10.1007/s11172-016-1640-4 WOS Scopus РИНЦ OpenAlex

Солодовниченко В.С. , Кряжев Ю.Г. , Арбузов А.Б. , Талзи В.П. , Антоничева Н.В. , Дроздов В.А. , Запевалова Е.С. , Лихолобов В.А.
Поливинилхлорид как предшественник для низкотемпературного синтеза углеродных материалов
Известия Академии наук. Серия химическая. 2016. №11. С.2712-2717. РИНЦ

Submitted:	May 24, 2016
Accepted:	Aug 15, 2016
Published print:	Nov 1, 2016
Published online:	May 17, 2017

Web of science:	WOS:000401572700023
Scopus:	2-s2.0-85019199718
Elibrary:	31027609
OpenAlex:	W2615246677

DB	Citing
Web of science	8
Scopus	13
Elibrary	4
OpenAlex	13