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Mechanochemical Synthesis of Nanocrystalline Nickel–Molybdenum Compounds and Their Morphology and Application in Catalysis: II. Effect of Mechanochemical Activation Parameters—Process Power Density and Exposure Time—on the Composition and Structure of Nickel–Molybdenum Compounds Full article

Journal Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210
Output data Year: 2014, Volume: 55, Number: 1, Pages: 121-129 Pages count : 9 DOI: 10.1134/S0023158414010042
Authors Knyazheva O. A. 1 , Baklanova O. N. 1 , Lavrenov A. V. 1 , Drozdov V. A. 1,2 , Leont’eva N. N. 1 , Vasilevich A. V. 1 , Shilova A. V. 1 , Likholobov V. A. 1,2
Affiliations
1 Institute of Hydrocarbon Processing, Siberian Branch, Russian Academy of Sciences, Omsk, Russia
2 Omsk State Technical University, Omsk, Russia

Abstract: The effect of mechanochemical activation parameters—process power density and the time of treatment of a mixture of nickel hydroxocarbonate NiCO3 · 2Ni(OH)2 · nH2O and ammonium paramolybdate (NH4)6Mo7O24 · 4H2O —on the phase composition, specific surface area, and morphology of mechanically activated products at different Ni : Mo atomic ratios was studied. It was found that, at a mechanochemical activation process power density of 6.2 W/g, layered transition metal molybdates (LTM compounds) with different amounts of crystal water were the constituents of the products, whereas the products mechanically activated at a power density of 28.0 W/g contained a mixture of LTM compounds and heteropoly compounds with the Anderson structure regardless of activation time
Cite: Knyazheva O.A. , Baklanova O.N. , Lavrenov A.V. , Drozdov V.A. , Leont’eva N.N. , Vasilevich A.V. , Shilova A.V. , Likholobov V.A.
Mechanochemical Synthesis of Nanocrystalline Nickel–Molybdenum Compounds and Their Morphology and Application in Catalysis: II. Effect of Mechanochemical Activation Parameters—Process Power Density and Exposure Time—on the Composition and Structure of Nickel–Molybdenum Compounds
Kinetics and Catalysis. 2014. V.55. N1. P.121-129. DOI: 10.1134/S0023158414010042 WOS Scopus РИНЦ OpenAlex
Original: Княжева О.А. , Бакланова О.Н. , Лавренов А.В. , Дроздов В.А. , Леонтьева Н.Н. , Василевич А.В. , Шилова А.В. , Лихолобов В.А.
Механохимический синтез нанокристаллических никель-молибденовых соединений, их морфологические особенности и применение в катализе. II. Влияние параметров механохимической активации – энергонапряженности процесса и времени воздействия – на состав и структуру никель-молибденовых соединений
Кинетика и катализ. 2014. Т.55. №1. С.126-134. DOI: 10.7868/S0453881114010043 РИНЦ OpenAlex
Dates:
Submitted: Feb 7, 2013
Published print: Dec 31, 2013
Published online: Feb 26, 2014
Identifiers:
Web of science: WOS:000332333700018
Scopus: 2-s2.0-84897746243
Elibrary: 21870891
OpenAlex: W2026015339
Citing:
DB Citing
Elibrary 3
Scopus 6
Web of science 7
OpenAlex 6
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