Mechanochemical Synthesis of Nanocrystalline Nickel–Molybdenum Compounds and Their Morphology and Application in Catalysis: II. Effect of Mechanochemical Activation Parameters—Process Power Density and Exposure Time—on the Composition and Structure of Nickel–Molybdenum Compounds Full article
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 2014, Volume: 55, Number: 1, Pages: 121-129 Pages count : 9 DOI: 10.1134/S0023158414010042 | ||||
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Abstract:
The effect of mechanochemical activation parameters—process power density and the time of
treatment of a mixture of nickel hydroxocarbonate NiCO3 · 2Ni(OH)2 · nH2O and ammonium paramolybdate (NH4)6Mo7O24 · 4H2O —on the phase composition, specific surface area, and morphology of mechanically activated products at different Ni : Mo atomic ratios was studied. It was found that, at a mechanochemical activation process power density of 6.2 W/g, layered transition metal molybdates (LTM compounds) with different amounts of crystal water were the constituents of the products, whereas the products mechanically activated at a power density of 28.0 W/g contained a mixture of LTM compounds and heteropoly compounds with the Anderson structure regardless of activation time
Cite:
Knyazheva O.A.
, Baklanova O.N.
, Lavrenov A.V.
, Drozdov V.A.
, Leont’eva N.N.
, Vasilevich A.V.
, Shilova A.V.
, Likholobov V.A.
Mechanochemical Synthesis of Nanocrystalline Nickel–Molybdenum Compounds and Their Morphology and Application in Catalysis: II. Effect of Mechanochemical Activation Parameters—Process Power Density and Exposure Time—on the Composition and Structure of Nickel–Molybdenum Compounds
Kinetics and Catalysis. 2014. V.55. N1. P.121-129. DOI: 10.1134/S0023158414010042 WOS Scopus РИНЦ OpenAlex
Mechanochemical Synthesis of Nanocrystalline Nickel–Molybdenum Compounds and Their Morphology and Application in Catalysis: II. Effect of Mechanochemical Activation Parameters—Process Power Density and Exposure Time—on the Composition and Structure of Nickel–Molybdenum Compounds
Kinetics and Catalysis. 2014. V.55. N1. P.121-129. DOI: 10.1134/S0023158414010042 WOS Scopus РИНЦ OpenAlex
Original:
Княжева О.А.
, Бакланова О.Н.
, Лавренов А.В.
, Дроздов В.А.
, Леонтьева Н.Н.
, Василевич А.В.
, Шилова А.В.
, Лихолобов В.А.
Механохимический синтез нанокристаллических никель-молибденовых соединений, их морфологические особенности и применение в катализе. II. Влияние параметров механохимической активации – энергонапряженности процесса и времени воздействия – на состав и структуру никель-молибденовых соединений
Кинетика и катализ. 2014. Т.55. №1. С.126-134. DOI: 10.7868/S0453881114010043 РИНЦ OpenAlex
Механохимический синтез нанокристаллических никель-молибденовых соединений, их морфологические особенности и применение в катализе. II. Влияние параметров механохимической активации – энергонапряженности процесса и времени воздействия – на состав и структуру никель-молибденовых соединений
Кинетика и катализ. 2014. Т.55. №1. С.126-134. DOI: 10.7868/S0453881114010043 РИНЦ OpenAlex
Dates:
Submitted: | Feb 7, 2013 |
Published print: | Dec 31, 2013 |
Published online: | Feb 26, 2014 |
Identifiers:
Web of science: | WOS:000332333700018 |
Scopus: | 2-s2.0-84897746243 |
Elibrary: | 21870891 |
OpenAlex: | W2026015339 |