Deep Oxidation of Methane on Alumina–Manganese and Pt-Containing Catalysts

Deep Oxidation of Methane on Alumina–Manganese and Pt-Containing Catalysts Full article

Journal

Journal of Catalysis
ISSN: 0021-9517 , E-ISSN: 1090-2694

Output data

Year: 2001, Volume: 198, Number: 2, Pages: 164-171 Pages count : 8 DOI: 10.1006/jcat.2000.3072

Tags

catalyst; manganese oxides; platinum; methane; deep oxidation.

Authors

Tsyrulnikov P.G. ¹ , Sal’nikov V.S. ¹ , Drozdov V.A. ¹ , Noskov A.S. ² , Chumakova N.A. ² , Ermolaev V.K. ² , Malakhova I.V. ²

Affiliations

1	Omsk Department of the Boreskov Institute of Catalysis SB RAS
2	Boreskov Institute of Catalysis SB RAS

The kinetics of deep methane oxidation was studied over a manganese–alumina catalyst and a reference catalyst—a tableted mechanical mixture of 2% Pt + γ -Al2O3. The reaction temperature ranged from 400 to 800◦C, the methane concentration was up to 4.5 vol%, and the oxygen content was up to stoichiometry. The higher the catalyst activity, the lower the probability for the homogeneous continuation of the catalytic reaction to proceed, even at 800◦C with the stoichiometry gas mixture composition. The distance over which alkyl peroxide catalysts escape from the catalyst surface under reaction conditions was estimated.

Tsyrulnikov P.G. , Sal’nikov V.S. , Drozdov V.A. , Noskov A.S. , Chumakova N.A. , Ermolaev V.K. , Malakhova I.V.
Deep Oxidation of Methane on Alumina–Manganese and Pt-Containing Catalysts
Journal of Catalysis. 2001. V.198. N2. P.164-171. DOI: 10.1006/jcat.2000.3072 WOS Scopus РИНЦ OpenAlex

Submitted:	Nov 30, 1999
Accepted:	Sep 18, 2000
Published online:	Feb 13, 2001
Published print:	Mar 1, 2001

Web of science:	WOS:000167650300002
Scopus:	2-s2.0-0035527209
Elibrary:	13366984
OpenAlex:	W2072287899

DB	Citing
Web of science	10
Scopus	9
Elibrary	10
OpenAlex	9