Thermodynamics of isomerization of butylenes: equilibrium compositions Full article
| Journal |
Petroleum Chemistry
ISSN: 0965-5441 , E-ISSN: 1531-8532 |
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| Output data | Year: 2001, Volume: 41, Number: 2, Pages: 126-130 Pages count : 5 | ||
| Tags | isobutene; butenes | ||
| Authors |
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| Affiliations |
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Abstract:
The disagreement in the literature data on equilibrium concentrations in the mixture of butylenes was demonstrated, and their correct values were calculated. The temperature dependence for the equilibrium constant of the isomerization of n-butylenes into isobutylene was derived. It was shown that the product compositions achieved in the manufacture of isobutylene by the skeleton isomerization of n-butylenes can be close to the equilibrium ratios. The experimental results obtained on F/Al2O3 and Nb2O5/Al2O3 catalysts are given.
Cite:
Lavrenov A.V.
, Ostrovskii N.M.
, Demanov Y.K.
Thermodynamics of isomerization of butylenes: equilibrium compositions
Petroleum Chemistry. 2001. V.41. N2. P.126-130. WOS Scopus РИНЦ
Thermodynamics of isomerization of butylenes: equilibrium compositions
Petroleum Chemistry. 2001. V.41. N2. P.126-130. WOS Scopus РИНЦ
Original:
Лавренов А.В.
, Островский Н.М.
, Деманов Ю.К.
Термодинамика изомеризации бутиленов. 1. Равновесные составы
Нефтехимия. 2001. Т.41. №2. С.144-148. РИНЦ
Термодинамика изомеризации бутиленов. 1. Равновесные составы
Нефтехимия. 2001. Т.41. №2. С.144-148. РИНЦ
Dates:
| Submitted: | Mar 31, 2000 |
Identifiers:
| Web of science: | WOS:000168338000009 |
| Scopus: | 2-s2.0-0035297140 |
| Elibrary: | 13375742 |