Mechanism of Iso-butane Alkylation by Butenes over H3PW12O40, H3PTiW11O39 and Zr Supported Catalysts

Mechanism of Iso-butane Alkylation by Butenes over H3PW12O40, H3PTiW11O39 and Zr Supported Catalysts Full article

Conference

2th International Congress on Catalysis 09-14 Jul 2000 , Granada
09-14 Jul 2000 , 12th International Congress on Catalysis 09-14 Jul 2000 , Granada

Journal

12th International Congress on Catalysis. Studies in Surface Science and Catalysis

Output data

Year: 2000, Volume: 130, Pages: 2543-2548 Pages count : 6

Authors

Paukshtis E.A. ¹ , Duplyakin V.K. ¹ , Finevich E.A. ¹ , Lavrenov A.V. ¹ , Kirillov V.L. ¹ , Kuznetsova V.A. ¹ , Likholobov V.A. ¹ , Bal’zhinimaev B.S. ¹

Affiliations

1	Boreskov Institute of Catalysis

In the present paper we report on the mechanism of i-butane alkylation by butenes using three types of well defined catalysts. The first type catalysts are composed heteropolyacids supported on a carbon support. The second type catalysts are represented by sulfated zirconia supported on silica. The third type catalysts were prepared with molecular design using alkyl zirconium complexes. Zirconium cations in coordinatively unsaturated state are shown to be responsible for alkylation. Reaction mechanism is suggested, involving carbenium ions and zirconium hydrides generation from i-butane.

Paukshtis E.A. , Duplyakin V.K. , Finevich E.A. , Lavrenov A.V. , Kirillov V.L. , Kuznetsova V.A. , Likholobov V.A. , Bal’zhinimaev B.S.
Mechanism of Iso-butane Alkylation by Butenes over H3PW12O40, H3PTiW11O39 and Zr Supported Catalysts
12th International Congress on Catalysis. Studies in Surface Science and Catalysis. 2000. V.130. P.2543-2548. Scopus

Scopus:

2-s2.0-0034350771

DB	Citing
Scopus	6