The Features of the CO Disproportionation Reaction over Iron-Containing Catalysts Prepared by Different Methods

The Features of the CO Disproportionation Reaction over Iron-Containing Catalysts Prepared by Different Methods Full article

Journal

Reaction Kinetics, Mechanisms and Catalysis
ISSN: 1878-5190 , E-ISSN: 1878-5204

Output data

Year: 2016, Volume: 117, Number: 1, Pages: 35-46 Pages count : 12 DOI: 10.1007/s11144-015-0936-y

Tags

Carbide cycle mechanism, Carbon deposits, Carbon nanofibers, CO disproportionation reaction, Fe-containing catalysts

Authors

Vedyagin A. A. ¹ , Mishakov I. V. ^1,2 , Tsyrulnikov P. G. ³

Affiliations

1	Boreskov Institute of Catalysis SB RAS, pr. Ac. Lavrentieva, 5, Novosibirsk, Russia 630090
2	National Research Tomsk Polytechnic University, Lenin av., 30, Tomsk, Russia 634050
3	Institute of Hydrocarbons Processing SB RAS, Neftezavodskaya str., 54, Omsk, Russia 644040

The peculiarities of the CO disproportionation reaction over iron-containing catalysts have been studied. The reaction is known to be reversible and resulting in a direct path to the formation of carbon deposits and CO2. The iron-containing catalysts (1–5 wt% of Fe) were prepared by three different methods: co-precipitation of Fe- and Al-containing precursors, impregnation of γ-Al2O3 support with iron nitrate, and solution combustion synthesis (SCS). The latter technique is based on self-propagating combustion of active component precursor with fuel additive deposited on surface of fiberglass. The synthesized samples were characterized with physicochemical methods and tested in CO disproportionation reaction within the temperature range of 120–600 °C. The co-precipitated catalyst 5 wt% Fe–Al2O3 showed the highest activity (45 % conversion of CO) which is much superior to that observed for other catalysts in this reaction. According to SEM, CO disproportionation reaction has resulted in carbon deposition in both amorphous and nanostructured forms. It was shown that preparative technique has significant effect on catalytic performance of iron-containing catalysts.

Vedyagin A.A. , Mishakov I.V. , Tsyrulnikov P.G.
The Features of the CO Disproportionation Reaction over Iron-Containing Catalysts Prepared by Different Methods
Reaction Kinetics, Mechanisms and Catalysis. 2016. V.117. N1. P.35-46. DOI: 10.1007/s11144-015-0936-y WOS Scopus РИНЦ AN OpenAlex

Published online:	Oct 12, 2015
Published print:	Jan 31, 2016

Web of science:	WOS:000368531300003
Scopus:	2-s2.0-84955690972
Elibrary:	26858731
Chemical Abstracts:	2015:1657836
OpenAlex:	W1937981203

DB	Citing
Web of science	8
Scopus	14
Elibrary	4
OpenAlex	14