Effect of the Acid–Base Properties of Zr,Al-Pillared Clays on the Catalytic Performances in the Reaction of Propylene Oxide with Methanol Научная публикация
Журнал |
Applied Catalysis B: Environmental
ISSN: 0926-3373 , E-ISSN: 1873-3883 |
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Вых. Данные | Год: 2011, Том: 104, Номер: 1-2, Страницы: 54-63 Страниц : 10 DOI: 10.1016/j.apcatb.2011.02.028 | ||||||||||
Ключевые слова | Methanol, Propylene glycol methyl ether, Propylene oxide, Zr,Al-pillared clays | ||||||||||
Авторы |
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Организации |
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Реферат:
A series of Zr,Al-pillared interlayered clays (Zr,Al-PILCs) have been prepared and characterized by X-ray diffraction, elemental analysis, FT-IR and N2-adsorption/desorption analyses, 27Al NMR(MAS), FT-IR spectroscopy using pyridine, PhCN and CDCl3 as probe molecules. It was found that textural and physicochemical properties of Zr,Al-PILCs depend on Zr content in clay. The relationship between the acid–base properties and catalytic performances of Zr,Al-PILCs was revealed in the synthesis of propylene glycol methyl ether from methanol and propylene oxide. The results show that the conversion of propylene oxide and the selectivity to 1-methoxy-2-propanol decrease with increasing the amount of zirconium in Zr,Al-PILCs due to the change in acid–base properties.
Библиографическая ссылка:
Timofeeva M.N.
, Panchenko V.N.
, Gil A.
, Doronin V.P.
, Golovin A.V.
, Andreev A.S.
, Likholobov V.A.
Effect of the Acid–Base Properties of Zr,Al-Pillared Clays on the Catalytic Performances in the Reaction of Propylene Oxide with Methanol
Applied Catalysis B: Environmental. 2011. V.104. N1-2. P.54-63. DOI: 10.1016/j.apcatb.2011.02.028 WOS Scopus РИНЦ CAPlusCA OpenAlex
Effect of the Acid–Base Properties of Zr,Al-Pillared Clays on the Catalytic Performances in the Reaction of Propylene Oxide with Methanol
Applied Catalysis B: Environmental. 2011. V.104. N1-2. P.54-63. DOI: 10.1016/j.apcatb.2011.02.028 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: | 29 нояб. 2010 г. |
Опубликована online: | 1 мар. 2011 г. |
Опубликована в печати: | 31 мар. 2011 г. |
Принята к публикации: | 22 нояб. 2011 г. |
Идентификаторы БД:
Web of science: | WOS:000290704500008 |
Scopus: | 2-s2.0-79954418310 |
РИНЦ: | 16999186 |
Chemical Abstracts: | 2011:480949 |
Chemical Abstracts (print): | 154:543043 |
OpenAlex: | W1967860492 |