Catalytic cracking of a mixture of vacuum gas oil and vegetable oil in the presence of mixed Full article
| Journal |
Russian Journal of Applied Chemistry
ISSN: 1070-4272 , E-ISSN: 1608-3296 |
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| Output data | Year: 2019, Volume: 92, Number: 10, Pages: 1383-1391 Pages count : 9 DOI: 10.1134/S1070427219100082 | ||
| Tags | mixed oxide, catalytic cracking, vegetable oil, hydrogen-transfer reactions | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Ministry of Science and Higher Education of the Russian Federation | V. 47 |
Abstract:
Effect of mixed Mg–Al oxides contained in catalysts on the distribution of target products formed
in cracking of a mixture of vacuum gas oil with sunfl ower oil was examined. It was found that the process of
deoxygenation of oxygen-containing compounds can be controlled by varying the molar ratio between magnesium
and aluminum in the mixed oxides. For catalyst samples containing mixed oxides with large Mg : Al molar ratios,
the content of carbon dioxide in inorganic products grows, which is indicative of the increased activity of the
decarboxylation reaction. In addition, the results of catalytic tests demonstrate that the highest conversion and
yield of the benzine fraction are observed for catalyst samples containing mixed oxides with small magnesiumto-
aluminum ratios of 0.32 : 1 and 0.49 : 1. A high activity of hydrogen-transfer reactions is observed for these
samples, which leads to a decrease in the yield of light olefi ns. Thus, it is advisable, for obtaining an increased
yield of C3 and C4 olefi ns, to include into the composition
Cite:
Lipin P.V.
, Potapenko O.V.
, Sorokina T.P.
, Doronin V.P.
Catalytic cracking of a mixture of vacuum gas oil and vegetable oil in the presence of mixed
Russian Journal of Applied Chemistry. 2019. V.92. N10. P.1383-1391. DOI: 10.1134/S1070427219100082 WOS Scopus РИНЦ OpenAlex
Catalytic cracking of a mixture of vacuum gas oil and vegetable oil in the presence of mixed
Russian Journal of Applied Chemistry. 2019. V.92. N10. P.1383-1391. DOI: 10.1134/S1070427219100082 WOS Scopus РИНЦ OpenAlex
Original:
Липин П.В.
, Потапенко О.В.
, Сорокина Т.П.
, Доронин В.П.
Каталитический крекинг смеси вакуумного газойля и растительного масла в присутствии добавки смешанного Mg-Al оксида различного состава
Журнал прикладной химии. 2019. Т.92. №10. С.1291-1300. DOI: 10.1134/S0044461819100086 РИНЦ OpenAlex
Каталитический крекинг смеси вакуумного газойля и растительного масла в присутствии добавки смешанного Mg-Al оксида различного состава
Журнал прикладной химии. 2019. Т.92. №10. С.1291-1300. DOI: 10.1134/S0044461819100086 РИНЦ OpenAlex
Dates:
| Submitted: | Mar 20, 2019 |
| Accepted: | Jul 3, 2019 |
| Published print: | Oct 1, 2019 |
| Published online: | Dec 11, 2019 |
Identifiers:
| Web of science: | WOS:000510661600008 |
| Scopus: | 2-s2.0-85076397418 |
| Elibrary: | 43221137 |
| OpenAlex: | W2994626033 |