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Palladium Supported on Carbon Nanoglobules as a Promising Catalyst for Selective Hydrogenation of Nitroarenes Научная публикация

Журнал Catalysis Letters
ISSN: 1011-372X , E-ISSN: 1572-879X
Вых. Данные Год: 2020, Том: 150, Номер: 3, Страницы: 888-900 Страниц : 13 DOI: 10.1007/s10562-019-02974-6
Ключевые слова Catalytic hydrogenation, Carbon nanoglobules, Palladium catalysts, Nitroarenes, Aromatic amines
Авторы Mironenko R.M. 1,2 , Belskaya O.B. 1,3 , Stepanova L.N. 1,2 , Gulyaeva T.I. 1 , Trenikhin M.V. 1,3 , Likholobov V.A. 4
Организации
1 Center of New Chemical Technologies of the Federal Research Center Boreskov Institute of Catalysis of Siberian Branch of the Russian Academy of Sciences
2 Dostoevsky Omsk State University
3 Omsk State Technical University
4 Federal Research Center Boreskov Institute of Catalysis

Информация о финансировании (1)

1 Российский фонд фундаментальных исследований 16-29-10742

Реферат: The catalysts 1 wt% palladium supported on carbon nanoglobules (CNGs) were shown to be highly active in the liquid-phase hydrogenation of various nitroarenes and provided nearly 100% selectivity to aromatic amines at complete conversion under mild conditions (323 K, 0.5 MPa, 1 h). The catalytic activity (in terms of turnover frequency and substrate conversion) and selectivity depend on the kind of CNGs support, catalyst preparation method and the reaction conditions (solvent nature). The Pd/CNGs catalyst can be repeatedly used while maintaining the same catalytic performance. The excellent performances of Pd/CNGs catalysts can be due to the globular morphology of the supports as well as the absence of micropores and pronounced surface defects.
Библиографическая ссылка: Mironenko R.M. , Belskaya O.B. , Stepanova L.N. , Gulyaeva T.I. , Trenikhin M.V. , Likholobov V.A.
Palladium Supported on Carbon Nanoglobules as a Promising Catalyst for Selective Hydrogenation of Nitroarenes
Catalysis Letters. 2020. V.150. N3. P.888-900. DOI: 10.1007/s10562-019-02974-6 WOS Scopus РИНЦ OpenAlex
Даты:
Поступила в редакцию: 12 авг. 2019 г.
Принята к публикации: 20 сент. 2019 г.
Опубликована online: 9 окт. 2019 г.
Опубликована в печати: 1 мар. 2020 г.
Идентификаторы БД:
Web of science: WOS:000513263600027
Scopus: 2-s2.0-85074401840
РИНЦ: 41684967
OpenAlex: W2980300199
Цитирование в БД:
БД Цитирований
Scopus 15
Web of science 9
OpenAlex 15
Альметрики: