Zinc Influence on the Formation and Properties of Pt/Mg(Zn)AlOx Catalysts Synthesized from Layered Hydroxides

Zinc Influence on the Formation and Properties of Pt/Mg(Zn)AlOx Catalysts Synthesized from Layered Hydroxides Full article

Journal

Journal of Catalysis
ISSN: 0021-9517 , E-ISSN: 1090-2694

Output data

Year: 2016, Volume: 341, Pages: 13-23 Pages count : 11 DOI: 10.1016/j.jcat.2016.06.006

Tags

EXAFS, Platinum catalysts, Propane dehydrogenation, XPS, Zinc containing layered double hydroxides

Authors

Belskaya O.B. ^1,2 , Stepanova L.N. ¹ , Gulyaeva T.I. ¹ , Erenburg S.B. ^3,4 , Trubina S.V. ³ , Kvashnina K. ⁵ , Nizovskii A.I. ^2,6 , Kalinkin A.V. ⁶ , Zaikovskii V.I. ^6,7 , Bukhtiyarov V.I. ^6,7 , Likholobov V.A. ^1,2

Affiliations

1	Institute of Hydrocarbons Processing SB RAS, Neftezavodskaya St., 54, 644040 Omsk, Russia
2	Omsk State Technical University, Mira Ave., 11, 644050 Omsk, Russia
3	Nikolaev Institute of Inorganic Chemistry SB RAS, Acad. Lavrentieva Ave., 3, 630090 Novosibirsk, Russia
4	Budker Institute of Nuclear Physics SB RAS, Acad. Lavrentieva Ave., 11, 630090 Novosibirsk, Russia
5	ESRF-The European Synchrotron, CS40220, 38043 Grenoble Cedex 9, France
6	Boreskov Institute of Catalysis SB RAS, Acad. Lavrentieva Ave., 5, 630090 Novosibirsk, Russia
7	Novosibirsk State University, Pirogova Str. 2, 630090 Novosibirsk, Russia

Funding (1)

Federal Agency for Scientific Organizations

V.46.2.8

Layered double hydroxides (LDH) containing Al3+, Mg2+ and Zn2+ cations with the ratios of Zn/(Mg + Zn) = 0, 0.05, 0.1, 0.2, 0.5, 0.7, and 1.0 were synthesized. The effect of zinc content on the phase composition of LDH and on the structural parameters, textural characteristics and acid–base properties of the corresponding mixed oxides were studied. This type of supports was used to obtain the non-acid platinum Pt/Mg(Zn)AlOx catalysts. The formation of supported platinum particles, their composition, dispersion and electronic state were examined by means of TPR, TEM, XPS, and EXAFS. The possibility to obtain the bimetallic PtZn particles, whose structure and strength of interaction with the support depend on the zinc content of the support, was demonstrated. It was found that the presence of zinc atoms in the platinum environment decreases the particle size of active metal and stabilizes platinum in the active metallic state ensuring a high activity of the catalyst in dehydrogenation of propane with the selectivity for propylene above 99%.

Belskaya O.B. , Stepanova L.N. , Gulyaeva T.I. , Erenburg S.B. , Trubina S.V. , Kvashnina K. , Nizovskii A.I. , Kalinkin A.V. , Zaikovskii V.I. , Bukhtiyarov V.I. , Likholobov V.A.
Zinc Influence on the Formation and Properties of Pt/Mg(Zn)AlOx Catalysts Synthesized from Layered Hydroxides
Journal of Catalysis. 2016. V.341. P.13-23. DOI: 10.1016/j.jcat.2016.06.006 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Mar 2, 2016
Accepted:	Jun 6, 2016
Published print:	Sep 1, 2016

Web of science:	WOS:000382408300002
Scopus:	2-s2.0-84976578874
Elibrary:	26835589
Chemical Abstracts:	2016:1014029
Chemical Abstracts (print):	165:317373
OpenAlex:	W2463231159

DB	Citing
Web of science	29
Scopus	35
Elibrary	15
OpenAlex	33