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A study on the interaction of manganese dioxide with ammonium chloride Научная публикация

Конференция 9-ая международная научно-техническая конференция "Техника и технология нефтехимического и нефтегазового производства"
26-28 февр. 2019 , Омск
Журнал AIP Conference Proceedings
ISSN: 0094-243X , E-ISSN: 1551-7616
Вых. Данные Год: 2019, Том: 2141, Страницы: 020023 Страниц : 6 DOI: 10.1063/1.5122042
Ключевые слова Interaction between MnO2 and NH4Cl, final products: MnCl2, Mn3N2, (NH4)2MnCl4∙2H2O and Mn8O10Cl3, TGA-DSC analysis, IR spectroscopy and XRD.
Авторы Osipov A.R. 1 , Kiselev A.D. 3 , Kraidenko R.I. 3 , Borisov V.A. 1,2
Организации
1 Center Of New Chemical Technologies BIC, 54, Neftezavodskaya Str., Omsk 644040, Russia
2 Omsk State Technical University, 11, Mira Pr., Omsk 644050, Russia
3 Institute of Light Materials and Technologies Ltd., 6/21, Leninsky Pr., Moscow 119049, Russia

Реферат: The MnO2:NH4Cl system is a component of the widely used Leclanche electrochemical cell. In addition, pyrolusite is among the main components of manganese ores. Quite promising is the chloride technology used for processing manganese-containing feed. In this paper, the interaction between manganese dioxide and ammonium chloride was studied. Final products of the interaction between MnO2 and NH4Cl are not only manganese(II) chloride, but also chloromanganates, nitrides and oxychlorides as the most thermodynamically favorable products. To understand the multistep nature of the process, the TGA-DSC analysis was carried out. The products were characterized by IR spectroscopy and XRD.
Библиографическая ссылка: Osipov A.R. , Kiselev A.D. , Kraidenko R.I. , Borisov V.A.
A study on the interaction of manganese dioxide with ammonium chloride
AIP Conference Proceedings. 2019. V.2141. P.020023. DOI: 10.1063/1.5122042 WOS Scopus РИНЦ OpenAlex
Даты:
Поступила в редакцию: 19 июл. 2019 г.
Опубликована online: 28 авг. 2019 г.
Идентификаторы БД:
Web of science: WOS:000516716100023
Scopus: 2-s2.0-85072128416
РИНЦ: 41674824
OpenAlex: W2970907319
Цитирование в БД:
БД Цитирований
Scopus 2
Web of science 2
OpenAlex 2
Альметрики: