Methods for Modifying a ZSM-5 Type Zeolite to Alter the Activity of the System of Hydrogen Transfer Reactions in the Cracking of Lower Aliphatic Alcohols Full article
| Journal |
Petroleum Chemistry
ISSN: 0965-5441 , E-ISSN: 1531-8532 |
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| Output data | Year: 2019, Volume: 59, Number: 7, Pages: 666-674 Pages count : 9 DOI: 10.1134/S0965544119070028 | ||
| Tags | alkali treatment; hydrogen transfer; modification with phosphorus; monohydric alcohols; ZSM-5 | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Ministry of Science and Higher Education of the Russian Federation | 46.2.4 |
Abstract:
Abstract: The influence of the alkali treatment of ZSM-5 zeolites with a silica ratio of 30 within the NaOH : SiO2 molar ratio of 0 : 230, as well as the modification of a ZSM-5 zeolite with phosphorus in the range of 0–8 wt %, on the physicochemical properties and activity in hydrogen transfer reactions in the case of conversion of aliphatic alcohols has been studied. The alkali treatment of the zeolite leads to a decrease in the zeolite silica ratio and a growth in the hydrogen transfer coefficient in the case of transformation of aliphatic alcohols. The modification of the zeolite with phosphorus is equivalent to an increase in the zeolite silica ratio, which leads to a decrease in the hydrogen transfer coefficient. © 2019, Pleiades Publishing, Ltd.
Cite:
Altynkovich E.O.
, Plekhova K.S.
, Potapenko O.V.
, Talzi V.P.
, Sorokina T.P.
, Doronin V.P.
Methods for Modifying a ZSM-5 Type Zeolite to Alter the Activity of the System of Hydrogen Transfer Reactions in the Cracking of Lower Aliphatic Alcohols
Petroleum Chemistry. 2019. V.59. N7. P.666-674. DOI: 10.1134/S0965544119070028 WOS Scopus РИНЦ OpenAlex
Methods for Modifying a ZSM-5 Type Zeolite to Alter the Activity of the System of Hydrogen Transfer Reactions in the Cracking of Lower Aliphatic Alcohols
Petroleum Chemistry. 2019. V.59. N7. P.666-674. DOI: 10.1134/S0965544119070028 WOS Scopus РИНЦ OpenAlex
Original:
Алтынкович Е.О.
, Плехова К.С.
, Потапенко О.В.
, Талзи В.П.
, Сорокина Т.П.
, Доронин В.П.
Способы модифицирования цеолита типа ZSM-5 для изменения активности системы реакций переноса водорода при крекинге низших алифатических спиртов
Нефтехимия. 2019. Т.59. №4. С.378-387. DOI: 10.1134/s0028242119040026 РИНЦ OpenAlex
Способы модифицирования цеолита типа ZSM-5 для изменения активности системы реакций переноса водорода при крекинге низших алифатических спиртов
Нефтехимия. 2019. Т.59. №4. С.378-387. DOI: 10.1134/s0028242119040026 РИНЦ OpenAlex
Dates:
| Published print: | Jul 1, 2019 |
| Published online: | Aug 7, 2019 |
Identifiers:
| Web of science: | WOS:000479289300002 |
| Scopus: | 2-s2.0-85070412653 |
| Elibrary: | 41677216 |
| OpenAlex: | W2966648805 |