Direct Synthesis of Propylene from Ethylene over Palladium Containing Catalysts: Influence of the Support Nature

Direct Synthesis of Propylene from Ethylene over Palladium Containing Catalysts: Influence of the Support Nature Full article

Journal

Advanced Materials Research
ISSN: 1022-6680

Output data

Year: 2015, Volume: 1085, Pages: 17-22 Pages count : 6 DOI: 10.4028/www.scientific.net/AMR.1085.17

Tags

Ethylene, propylene, palladium oxide, rhenium oxide, support acidity

Authors

Sayfulina Luiza F. ¹ , Buluchevskiy Eygeny A. ¹ , Lavrenov Alexander V. ¹ , Gulyaeva Tatyana I. ¹ , Trenikhin Michael V. ¹ , Protasova Olga V. ¹ , Gerasimov Eugeny Yu. ² , Gulyaev Roman V. ² , Drozdov Vladimir A. ¹

Affiliations

1	Institute of Hydrocarbons Processing SB RAS, Neftezavodskaya str. 54, Omsk, 644040 Russia
2	Boreskov Institute of Catalysis SB RAS, Pr. Lavrentieva 5, Novosibirsk, 630090 Russia

An influence of support acidity on the dimerization function on Pd-containing catalysts was studied. After addition of Re2O7 to PdO/SZ as ethylene dimerization catalyst with high butene-2 selectivity the obtained PdO-Re2O7/SZ catalyst was tested in direct synthesis of propylene from ethylene under mild conditions (40°C and atmospheric pressure). Propylene yield was approximately 45%, which is close to equilibrium one

Sayfulina L.F. , Buluchevskiy E.A. , Lavrenov A.V. , Gulyaeva T.I. , Trenikhin M.V. , Protasova O.V. , Gerasimov E.Y. , Gulyaev R.V. , Drozdov V.A.
Direct Synthesis of Propylene from Ethylene over Palladium Containing Catalysts: Influence of the Support Nature
Advanced Materials Research. 2015. V.1085. P.17-22. DOI: 10.4028/www.scientific.net/AMR.1085.17 РИНЦ OpenAlex

Submitted:	Jul 2, 2014
Accepted:	Oct 11, 2014
Published online:	Oct 2, 2015

Elibrary:	29790227
OpenAlex:	W2044245897

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