Effect of the Modifier on the Catalytic Properties and Thermal Stability of Ru–Cs(Ba)/Sibunit Catalyst for Ammonia Decomposition

Effect of the Modifier on the Catalytic Properties and Thermal Stability of Ru–Cs(Ba)/Sibunit Catalyst for Ammonia Decomposition Научная публикация

Журнал

Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210

Вых. Данные

Год: 2019, Том: 60, Номер: 3, Страницы: 372-379 Страниц : 8 DOI: 10.1134/S0023158419030029

Ключевые слова

Ru–Ba(Cs)/C catalysts, ammonia decomposition, activity, resistance to methanation, Sibunit

Авторы

Borisov V.A. ¹ , Iost K.N. ¹ , Petrunin D.A. ² , Temerev V.L. ¹ , Muromtsev I.V. ¹ , Arbuzov A.B. ¹ , Trenikhin M.V. ¹ , Gulyaeva T.I. ¹ , Smirnova N.S. ³ , Shlyapin D.A. ¹ , Tsyrul'nikov P.G. ¹

Организации

1	Institute of Hydrocarbons Processing, Siberian Branch, Russian Academy of Sciences, Omsk, 644040 Russia
2	Omsk State Technical University, Omsk, 644050 Russia
3	Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991 Russia

Информация о финансировании (1)

Министерство науки и высшего образования Российской Федерации

46.2.5

Based on the Sibunit carbon composite, Ru–Cs(Ba)/Sibunit catalysts with Cs (Ba) : Ru molar ratios of 0.5, 1.5, and 2.5 were obtained. The catalytic activity of the obtained promoted catalysts in the decomposition of ammonia and their thermal resistance to methanation are compared. In the reaction of ammonia decomposition, the specific activity (Wsp) of barium-containing catalysts proved to be 2 times lower than the specific activity of cesium-containing samples with the same molar M : Ru ratio. Thus, Wsp at 500°С was 29.4 mmol H2 min–1 for 0.5Cs–Ru/Sibunit and 15.4 mmol H2 min–1 for 0.5Ba–Ru/Sibunit. It was shown that the introduction of barium at molar ratios Ba : Ru = of 0.5–2.5 significantly increases the thermal stability of the samples defined as the ratio of the weight of hydrogen obtained on the catalyst to the weight of carbon subjected to methanation. There is 52 g H2 for nonpromoted Ru/Sibunit catalyst, 370 g H2 for the 0.5Ba–Ru/Sibunit sample, 200 g H2 for the 1.5Ba–Ru/Sibunit sample, and 150 g H2 for the 2.5Ba–Ru/Sibunit sample per 1 g of carbon loss.

Borisov V.A. , Iost K.N. , Petrunin D.A. , Temerev V.L. , Muromtsev I.V. , Arbuzov A.B. , Trenikhin M.V. , Gulyaeva T.I. , Smirnova N.S. , Shlyapin D.A. , Tsyrul'nikov P.G.
Effect of the Modifier on the Catalytic Properties and Thermal Stability of Ru–Cs(Ba)/Sibunit Catalyst for Ammonia Decomposition
Kinetics and Catalysis. 2019. V.60. N3. P.372-379. DOI: 10.1134/S0023158419030029 WOS Scopus РИНЦ OpenAlex

Борисов В.А. , Иост К.Н. , Петрунин Д.А. , Темерев В.Л. , Муромцев И.В. , Арбузов А.Б. , Тренихин М.В. , Гуляева Т.И. , Смирнова Н.С. , Шляпин Д.А. , Цырульников П.Г.
Влияние природы модификатора на каталитические свойства и термическую стабильность катализаторов разложения аммиакаRu–Cs(Ba)/Сибунит
Кинетика и катализ. 2019. Т.60. №3. С.394-402. РИНЦ

Поступила в редакцию:	21 сент. 2018 г.
Принята к публикации:	28 дек. 2018 г.
Опубликована в печати:	1 мая 2019 г.
Опубликована online:	18 июн. 2019 г.

Web of science:	WOS:000472087300015
Scopus:	2-s2.0-85067447071
РИНЦ:	41692377
OpenAlex:	W2949271821

БД	Цитирований
Scopus	10
Web of science	7
OpenAlex	11