Catalytic Cracking of Cyclohexane and 1-Hexene Mixtures on Mono-, Bi-, and Tri-Zeolite Catalysts Full article
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2019, Volume: 60, Number: 1, Pages: 74-86 Pages count : 13 DOI: 10.1134/S0023158419010117 | ||
| Tags | catalytic cracking, ethylene, propylene, butylenes, narrow-porous zeolites, ZSM-5, mordenite, ferrierite, Y | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Ministry of Science and Higher Education of the Russian Federation | 46.2.4 |
Abstract:
⎯The effects of temperature (540–640°C), weight hour space velocity (1.0–7.0 h–1), and steam :
raw material ratios (0–2.5) on the yield of C2–C4 olefins, conversion, and octane characteristics in the cracking of a mixture of model hydrocarbons (cyclohexane and 1-hexene) were studied. The influence of the structure of zeolites in mono-, bi-, and tri-zeolite catalysts on the distribution of cracking products was examined.
It was found that the combination of catalyst components in bi- and tri-zeolite systems makes it possible to increase
the efficiency of the consecutive cracking of hydrocarbons (C6–C12 → C4–C8 → C3–C6 → C2–C4) according to
the following reaction scheme: matrix → ZSM-5 → FER. The maximum total yield of C2–C4 olefins
(50.2 wt % at a conversion of 75.5%) was achieved with the use of a bi-zeolite catalyst of ZSM-5 + FER
Cite:
Potapenko O.V.
, Khudyakov M.S.
, Altynkovich E.O.
, Plekhova K.S.
, Sorokina T.P.
, Doronin V.P.
Catalytic Cracking of Cyclohexane and 1-Hexene Mixtures on Mono-, Bi-, and Tri-Zeolite Catalysts
Kinetics and Catalysis. 2019. Т.60. №1. С.74-86. DOI: 10.1134/S0023158419010117 WOS Scopus РИНЦ OpenAlex
Catalytic Cracking of Cyclohexane and 1-Hexene Mixtures on Mono-, Bi-, and Tri-Zeolite Catalysts
Kinetics and Catalysis. 2019. Т.60. №1. С.74-86. DOI: 10.1134/S0023158419010117 WOS Scopus РИНЦ OpenAlex
Original:
Потапенко О.В.
, Худяков М.С.
, Алтынкович Е.О.
, Плехова К.С.
, Сорокина Т.П.
, Доронин В.П.
Каталитический крекинг смесей циклогексана и гексена-1 на моно-, би- и трицеолитных катализаторах
Кинетика и катализ. 2019. Т.60. №1. С.93-107. РИНЦ
Каталитический крекинг смесей циклогексана и гексена-1 на моно-, би- и трицеолитных катализаторах
Кинетика и катализ. 2019. Т.60. №1. С.93-107. РИНЦ
Dates:
| Submitted: | May 14, 2018 |
| Published print: | Jan 1, 2019 |
| Published online: | May 15, 2019 |
Identifiers:
| Web of science: | WOS:000468063400010 |
| Scopus: | 2-s2.0-85066031675 |
| Elibrary: | 41657516 |
| OpenAlex: | W2946221438 |