Controlling the Ratio of the Reactions of Intermolecular Hydrogen Transfer and Cracking on Apparatuses with Fixed and Circulating Catalytic Beds Full article
Journal |
Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555 |
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Output data | Year: 2019, Volume: 11, Number: 2, Pages: 154-161 Pages count : 8 DOI: 10.1134/S2070050419020090 | ||||
Tags | catalytic cracking, hydrogen-transfer reactions, circulating catalytic bed, olefins, deuterated hydrocarbons | ||||
Authors |
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Affiliations |
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Funding (1)
1 | Ministry of Science and Higher Education of the Russian Federation | 46.2.4 |
Abstract:
The effect the main parameters (temperature, pressure, and dilution of the reaction medium with
an inert gas) of such catalytic processes as the cracking of vacuum gasoil and the hydrogenless refining and
cracking of gasoline fractions have on the ratio of the selectivity of the cracking and intermolecular hydrogentransfer reactions is studied. Control over the ratio of these reactions allows products to be obtained according to the requirements for processing raw materials. An increase in the time of raw material–catalyst contact, a reduction in the degree of diluting the reaction mixture with an inert gas, and a rise in pressure result in greater selectivity for hydrogen-transfer reactions. Experiments are performed on apparatuses with fixed and circulating beds of zeolite-containing catalysts. The transformation of raw materials containing deuterated compounds is investigated
Cite:
Potapenko O.V.
, Lutchenko A.S.
, Doronin V.P.
, Sorokina T.P.
, Plekhanov M.A.
, Gur’evskikh S.Y.
, Khrapov D.V.
Controlling the Ratio of the Reactions of Intermolecular Hydrogen Transfer and Cracking on Apparatuses with Fixed and Circulating Catalytic Beds
Catalysis in Industry. 2019. Т.11. №2. С.154-161. DOI: 10.1134/S2070050419020090 WOS Scopus РИНЦ OpenAlex
Controlling the Ratio of the Reactions of Intermolecular Hydrogen Transfer and Cracking on Apparatuses with Fixed and Circulating Catalytic Beds
Catalysis in Industry. 2019. Т.11. №2. С.154-161. DOI: 10.1134/S2070050419020090 WOS Scopus РИНЦ OpenAlex
Original:
Потапенко О.В.
, Лутченко А.С.
, Доронин В.П.
, Сорокина Т.П.
, Плеханов М.А.
, Гурьевских С.Ю.
, Храпов Д.В.
Регулирование соотношения вклада реакций крекинга и межмолекулярного переноса водорода в процессе крекинга бензиновых фракций на установках с неподвижным и циркулирующим слоем катализатора
Катализ в промышленности. 2018. Т.18. №6. С.48-54. DOI: 10.18412/1816-0387-2018-6-48-54 РИНЦ OpenAlex
Регулирование соотношения вклада реакций крекинга и межмолекулярного переноса водорода в процессе крекинга бензиновых фракций на установках с неподвижным и циркулирующим слоем катализатора
Катализ в промышленности. 2018. Т.18. №6. С.48-54. DOI: 10.18412/1816-0387-2018-6-48-54 РИНЦ OpenAlex
Dates:
Submitted: | Jun 14, 2018 |
Accepted: | Aug 27, 2018 |
Published print: | Apr 1, 2019 |
Published online: | Jun 25, 2019 |
Identifiers:
Web of science: | WOS:000472891400009 |
Scopus: | 2-s2.0-85067918564 |
Elibrary: | 41685930 |
OpenAlex: | W2953813635 |