Homogeneous High-Temperature Oxidation of Methane Научная публикация
| Журнал |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
||||
|---|---|---|---|---|---|
| Вых. Данные | Год: 2007, Том: 91, Номер: 2, Страницы: 273-282 Страниц : 10 DOI: 10.1007/s11144-007-5158-5 | ||||
| Ключевые слова | Homogeneous reactions, Kinetics, Lean mixtures, Methane oxidation | ||||
| Авторы |
|
||||
| Организации |
|
Реферат:
The kinetics of homogeneous deep oxidation of methane in lean mixtures (up to 2 vol % CH4 in air) in ceramic tubes and fixed beds of ceramic spheres was studied. Experiments with the homogeneous reaction have shown that the methane oxidation occurs via a consecutive scheme through CO formation. The reaction rate of CH4 oxidation was found to depend upon the equivalent pass diameter with a significant reaction inhibition in packing of small tubes and spheres, reflecting the influence of mass transfer on the radical-chain termination at the ceramic surfaces. It was also found that CO oxidation practically does not depend upon the mass exchange conditions, but it is visibly inhibited by methane. Recommended kinetic equations and their parameters are presented.
Библиографическая ссылка:
Slepterev A.A.
, Salnikov V.S.
, Tsyrulnikov P.G.
, Noskov A.S.
, Tomilov V.N.
, Chumakova N.A.
, Zagoruiko A.N.
Homogeneous High-Temperature Oxidation of Methane
Reaction Kinetics and Catalysis Letters. 2007. V.91. N2. P.273-282. DOI: 10.1007/s11144-007-5158-5 WOS Scopus РИНЦ CAPlusCA OpenAlex
Homogeneous High-Temperature Oxidation of Methane
Reaction Kinetics and Catalysis Letters. 2007. V.91. N2. P.273-282. DOI: 10.1007/s11144-007-5158-5 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Опубликована online: | 11 авг. 2007 г. |
| Опубликована в печати: | 31 авг. 2007 г. |
Идентификаторы БД:
| Web of science: | WOS:000248818700010 |
| Scopus: | 2-s2.0-34547903828 |
| РИНЦ: | 13549230 |
| Chemical Abstracts: | 2007:898320 |
| Chemical Abstracts (print): | 150:194958 |
| OpenAlex: | W1971229526 |