Physicochemical Properties and Catalytic Activity of Metal–Carbon Carrier Composite Materials Full article
Journal |
Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X |
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Output data | Year: 2017, Volume: 91, Number: 7, Pages: 1197-1203 Pages count : 7 DOI: 10.1134/S0036024417070172 | ||||||
Tags | composite materials, carbon black, Sibunit, carbon nanotubes, catalytic activity | ||||||
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Abstract:
Composite metal–carbon materials are created on the basis of different kinds of carbon (multiwall
carbon nanotubes, carbon black, Sibunit carbon–carbon material) and metals (Ag, Ni, Co), and their physicochemical and catalytic properties are investigated. It is shown that interaction between metals and carbon carriers proceeds not only with the functional groups on the surfaces of the carriers, but also through a system of –C–C– conjugated bonds. Silver deposited on the surface of a carbon carrier has a crystalline structure (dcr = 10–15 nm), while nickel has an amorphous lamellar structure. Based on quantum-chemical calculations using the density functional theory, it is shown that cumene oxidation occurs via a homogeneous–heterogeneous mechanism.
Cite:
Kobotaeva N.S.
, Skorokhodova T.S.
, Razd’yakonova G.I.
, Poleshchuk O.K.
Physicochemical Properties and Catalytic Activity of Metal–Carbon Carrier Composite Materials
Russian Journal of Physical Chemistry A. 2017. V.91. N7. P.1197-1203. DOI: 10.1134/S0036024417070172 WOS Scopus РИНЦ
Physicochemical Properties and Catalytic Activity of Metal–Carbon Carrier Composite Materials
Russian Journal of Physical Chemistry A. 2017. V.91. N7. P.1197-1203. DOI: 10.1134/S0036024417070172 WOS Scopus РИНЦ
Original:
Коботаева Н.С.
, Скороходова Т.С.
, Раздьяконова Г.И.
, Полещук О.Х.
Физико-химические свойства и каталитическая активность композиционных материалов “металл – углеродный носитель”
Журнал физической химии. 2017. Т.91. №7. С.1124-1131. DOI: 10.7868/S0044453717070184 РИНЦ
Физико-химические свойства и каталитическая активность композиционных материалов “металл – углеродный носитель”
Журнал физической химии. 2017. Т.91. №7. С.1124-1131. DOI: 10.7868/S0044453717070184 РИНЦ
Dates:
Submitted: | Jun 16, 2016 |
Published online: | Jun 15, 2017 |
Published print: | Jul 1, 2017 |
Identifiers:
Web of science | WOS:000403501200007 |
Scopus | 2-s2.0-85020819201 |
Elibrary | 31023673 |
OpenAlex | W2626504324 |