Isomerization of n-hexane over bifunctional Pt/SO4/ZrO2 catalysts Full article
Journal |
Petroleum Chemistry
ISSN: 0965-5441 , E-ISSN: 1531-8532 |
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Output data | Year: 2009, Volume: 49, Number: 6, Pages: 473-480 Pages count : 8 DOI: 10.1134/s096554410906005x | ||
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Abstract:
The catalytic properties of model Pt/SiO2 and Pt/Al2O3 catalysts and their physical mixtures with
SO4/ZrO2 in the reaction of n-hexane isomerization have been studied. Significant effects of the influence of the platinum state on the characteristics of isomerization on the catalysts and their physical mixtures with SO4/ZrO2 have been revealed. The observed changes in catalytic performance of the mixed catalysts have been explained from the position of a bifunctional mechanism with the participation of ionic platinum promoting the formation of hydride ions, which play an important role in the activation of transformations of intermediates in isomerization reactions.
Cite:
Smolikov M.D.
, Dzhikiya O.V.
, Zatolokina E.V.
, Kir’yanov D.I.
, Belyi A.S.
Isomerization of n-hexane over bifunctional Pt/SO4/ZrO2 catalysts
Petroleum Chemistry. 2009. V.49. N6. P.473-480. DOI: 10.1134/s096554410906005x WOS Scopus РИНЦ
Isomerization of n-hexane over bifunctional Pt/SO4/ZrO2 catalysts
Petroleum Chemistry. 2009. V.49. N6. P.473-480. DOI: 10.1134/s096554410906005x WOS Scopus РИНЦ
Original:
Смоликов М.Д.
, Джикия О.В.
, Затолокина Е.В.
, Кирьянов Д.И.
, Белый А.С.
Изомеризация н-гексана на бифункциональных Pt/SO42-/ZrO2 катализаторах
Нефтехимия. 2009. Т.49. №6. С.488-495. РИНЦ
Изомеризация н-гексана на бифункциональных Pt/SO42-/ZrO2 катализаторах
Нефтехимия. 2009. Т.49. №6. С.488-495. РИНЦ
Dates:
Submitted: | Mar 19, 2009 |
Published print: | Nov 1, 2009 |
Published online: | Dec 3, 2009 |
Identifiers:
Web of science | WOS:000272383400005 |
Scopus | 2-s2.0-72449181762 |
Elibrary | 15308141 |
OpenAlex | W2463166130 |