A Study of the Homogeneous Oxidation of Low-Concentration Methane-Containing Gases at High Temperatures Full article
Journal |
Russian Journal of Applied Chemistry
ISSN: 1070-4272 , E-ISSN: 1608-3296 |
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Output data | Year: 2012, Volume: 85, Number: 10, Pages: 1570-1576 Pages count : 7 DOI: 10.1134/S1070427212100151 | ||||||
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Abstract:
It is shown that homogeneous oxidation of methane in air in a flow-reactor at methane concentrations of 0.5–2.0 vol %, temperatures of 700–1100°C, and contact time of 0.024–0.384 s occurs via formation of CO whose concentration passes through a maximum with increasing temperature. The selectivity of methane oxidation to CO reaches values of 70–90%. The degree of methane conversion depends on reactor packing and reactor diameter, which suggests that the process occurs by the radical-chain mechanism.
Cite:
Slepterev A.A.
, Tsyrulʹnikov P.G.
, Salʹnikov V.S.
, Zagoruiko A.N.
A Study of the Homogeneous Oxidation of Low-Concentration Methane-Containing Gases at High Temperatures
Russian Journal of Applied Chemistry. 2012. V.85. N10. P.1570-1576. DOI: 10.1134/S1070427212100151 WOS Scopus РИНЦ
A Study of the Homogeneous Oxidation of Low-Concentration Methane-Containing Gases at High Temperatures
Russian Journal of Applied Chemistry. 2012. V.85. N10. P.1570-1576. DOI: 10.1134/S1070427212100151 WOS Scopus РИНЦ
Original:
Слептерев А.А.
, Цырульников П.Г.
, Сальников В.С.
, Загоруйко А.Н.
Исследование гомогенного окисления низкоконцентрированных метансодержащих газов при высоких температурах
Журнал прикладной химии. 2012. Т.85. №10. С.1636-1643. РИНЦ
Исследование гомогенного окисления низкоконцентрированных метансодержащих газов при высоких температурах
Журнал прикладной химии. 2012. Т.85. №10. С.1636-1643. РИНЦ
Dates:
Submitted: | Dec 18, 2011 |
Published print: | Sep 30, 2012 |
Published online: | Nov 15, 2012 |
Identifiers:
Web of science | WOS:000311317600015 |
Scopus | 2-s2.0-84872065022 |
Elibrary | 20485283 |
Chemical Abstracts | 2012:1705599 |
Chemical Abstracts (print) | 158:40398 |
OpenAlex | W2079523718 |