Molecular design of precursor in the synthesis of catalytic nanocomposite system Pt-Al203 Full article
Journal |
Smart Nanocomposites
ISSN: 1949-4823 |
||||
---|---|---|---|---|---|
Output data | Year: 2011, Volume: 1, Number: 2, Pages: 99-133 Pages count : 34 | ||||
Authors |
|
||||
Affiliations |
|
Abstract:
The effect of the transformation sequence of metal complex precursor at the early stages of catalyst preparation on the state of platinum nanoparticles composing the active surface of the finished catalyst is demonstrated using the formation of catalytic nanocomposite system Pt/АЬОз as an example. The existing views on the nature of chemical binding between metal complexes and the support surface are reported. Approaches to quantitative differentiation of the ion-exchangeable (outer-sphere) and coordinatively bound (inner-sphere) adsorbed metal complex species, determination of their chemical composition, and synthesis of catalysts from the supported precursor uniformly interacting with the support are considered.
Cite:
Belskaya O.B.
, Duplyakin V.K.
, Likholobov V.A.
Molecular design of precursor in the synthesis of catalytic nanocomposite system Pt-Al203
Smart Nanocomposites. 2011. V.1. N2. P.99-133. РИНЦ
Molecular design of precursor in the synthesis of catalytic nanocomposite system Pt-Al203
Smart Nanocomposites. 2011. V.1. N2. P.99-133. РИНЦ
Identifiers:
Elibrary | 25072237 |
Citing:
DB | Citing |
---|---|
Elibrary | 12 |