Synthesis and study of Pt(Pd)-containing WO3/ZrO2 catalysts for isomerization of n-heptane
Full article
| Common |
Language:
Английский,
Genre:
Full article,
Status:
Published,
Source type:
Original
|
| Conference |
7-ая международная научно-техническая конференция "Техника и технология нефтехимического и нефтегазового производства"
24-28 Apr 2017
,
Омск
|
| Journal |
AIP Conference Proceedings
ISSN: 0094-243X
, E-ISSN: 1551-7616
|
| Output data |
Year: 2017,
Volume: 1876,
Article number
: 020005,
Pages count
: 7
DOI:
10.1063/1.4998825
|
| Authors |
Shkurenok V.A.
1
,
Smolikov M.D.
1,2
,
Yablokova S.S.
1
,
Kir’yanov D.I.
1
,
Kayumova T.R.
2
,
Muromtsev I.V.
1
,
Belyi A.S.
1,2
|
| Affiliations |
| 1 |
Institute of Hydrocarbons Processing SB RAS, Omsk 644040, Russian Federation
|
| 2 |
Omsk State Technical University, Omsk 644050, Russian Federation
|
|
Funding (1)
|
1
|
Russian Foundation for
Basic Research
|
16-43-550196 r_a
|
The effect of zirconia precursor in Pt-containing WO3/ZrO2 catalysts on isomerization of n-heptane was studied. Samples synthesized with zirconium sulfate as a ZrO2 precursor were shown to be more active in comparison with those synthesized from zirconium oxychloride. The enhanced activity of samples synthesized from zirconium sulfate is caused by a residual (1–1.3 wt. %) content of sulfate ions in the catalysts, which increases the catalyst acidity; as a result, the samples synthesized with zirconium oxychloride as a ZrO2 precursor are more selective. Characteristics of WO3/ZrO2 catalysts containing Pt or Pd as a metallic component were compared in n-heptane isomerization. The use of Pd as a hydrogenating component of tungstated zirconia catalysts was shown to improve the performance of n-heptane isomerization in comparison with the catalysts where the metallic component was represented by Pt.