Hydroxylation of Benzene with Oxygen and Hydrogen over Catalysts Containing Group VIII Metals and Heteropoly Compounds Full article
Journal |
Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308 |
||||||
---|---|---|---|---|---|---|---|
Output data | Year: 2005, Volume: 99, Number: 1-2, Pages: 193-198 Pages count : 6 DOI: 10.1016/j.cattod.2004.09.040 | ||||||
Tags | Benzene, Hydrogen, Oxidation, Oxygen, Palladium, Platinum | ||||||
Authors |
|
||||||
Affiliations |
|
Abstract:
The vapor phase hydroxylation of benzene to phenol with a mixture of oxygen and hydrogen over silica supported bi-component catalysts containing Group VIII metals (M) and heteropoly compounds (HPC) was investigated. The productivity of the catalysts was ascertained for various metal and HPC combinations and a range of reaction conditions. The Pt–PMo12/SiO2 and Pd–PMo12/SiO2 catalysts of optimal composition provide up to 380 mol phenol/g-atom Pt or Pd/h. The observed catalysis appears to be associated with an interface between metal particles and those of the heteropoly compound, as illustrated by an HREM image of a Pt–PMo12/SiO2 sample.
Cite:
Kuznetsova N.I.
, Kuznetsova L.I.
, Likholobov V.A.
, Pez G.P.
Hydroxylation of Benzene with Oxygen and Hydrogen over Catalysts Containing Group VIII Metals and Heteropoly Compounds
Catalysis Today. 2005. V.99. N1-2. P.193-198. DOI: 10.1016/j.cattod.2004.09.040 WOS Scopus РИНЦ
Hydroxylation of Benzene with Oxygen and Hydrogen over Catalysts Containing Group VIII Metals and Heteropoly Compounds
Catalysis Today. 2005. V.99. N1-2. P.193-198. DOI: 10.1016/j.cattod.2004.09.040 WOS Scopus РИНЦ
Dates:
Published print: | Dec 31, 2004 |
Identifiers:
Web of science | WOS:000228114200024 |
Scopus | 2-s2.0-14644415980 |
Elibrary | 13488577 |
Chemical Abstracts | 2005:224831 |
Chemical Abstracts (print) | 142:448563 |
OpenAlex | W2073651226 |